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a Laser Plasma Division, Raja Ramanna Centre for Advanced Technology, Indore, MP 452013, India. b Homi Bhabha National Institute, Training School Complex, Anushaktinagar, Mumbai, MH 400094, India. c Department of Mechanical Engineering, Indian Institute of Technology Bombay, Mumbai, MH 400076,India. d Department of Condensed Matter Physics & Materials Science, Tata Institute of FundamentalResearch, Mumbai, MH 400005, India. e Solid State Physics Division, Bhabha Atomic Research Centre,Mumbai, MH 400085, India. f Advanced Photon Source, Argonne National Laboratory, 9700 South CassAvenue, Lemont, IL 60439, USA. g Center for Research in Nano Technology and Science, Indian Instituteof Technology Bombay, Mumbai, MH 400076,India
Published:2023,
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Ranjana Rathore, Himanshu Singhal, Vivek Dwij, Mayanak K Gupta, Abhishek Pathak, Juzer Ali Chakera, Ranjan Mittal, Aditya Prasad Roy, Arun Babu, Ruta Kulkarni, A Thamizhavel, Ayman H Said, Dipanshu Bansal. 2023: Nonlocal Probing of Amplitude Mode Dynamics in Charge-Density-Wave Phase of EuTe4. 超快科学, Vol 3(6).
Ranjana Rathore, Himanshu Singhal, Vivek Dwij, Mayanak K Gupta, Abhishek Pathak, Juzer Ali Chakera, Ranjan Mittal, Aditya Prasad Roy, Arun Babu, Ruta Kulkarni, A Thamizhavel, Ayman H Said, Dipanshu Bansal. 2023: Nonlocal Probing of Amplitude Mode Dynamics in Charge-Density-Wave Phase of EuTe4. Ultrafast Science, Vol 3(6).
Ranjana Rathore, Himanshu Singhal, Vivek Dwij, Mayanak K Gupta, Abhishek Pathak, Juzer Ali Chakera, Ranjan Mittal, Aditya Prasad Roy, Arun Babu, Ruta Kulkarni, A Thamizhavel, Ayman H Said, Dipanshu Bansal. 2023: Nonlocal Probing of Amplitude Mode Dynamics in Charge-Density-Wave Phase of EuTe4. 超快科学, Vol 3(6). DOI: 10.34133/ultrafastscience.0041
Ranjana Rathore, Himanshu Singhal, Vivek Dwij, Mayanak K Gupta, Abhishek Pathak, Juzer Ali Chakera, Ranjan Mittal, Aditya Prasad Roy, Arun Babu, Ruta Kulkarni, A Thamizhavel, Ayman H Said, Dipanshu Bansal. 2023: Nonlocal Probing of Amplitude Mode Dynamics in Charge-Density-Wave Phase of EuTe4. Ultrafast Science, Vol 3(6). DOI: 10.34133/ultrafastscience.0041
Amplitude mode is collective excitation emerging from frozen lattice distortions below the charge-density-wave (CDW) transition temperature TCDW and relates to the order parameter. Generally
the amplitude mode is non-polar (symmetry-even) and does not interact with incoming infrared photons. However
if the amplitude mode is polar (symmetry-odd)
it can potentially couple with incoming photons
thus forming a coupled phonon–polariton quasiparticle that can travel with light-like speed beyond the optically excited region. Here
we present the amplitude mode dynamics far beyond the optically excited depth of ∼150 nm in the CDW phase of ∼10-μm-thick single-crystal EuTe4 using time-resolved x-ray diffraction. The observed oscillations of the CDW peak
triggered by photoexcitation
occur at the amplitude mode frequency ωAM. However
the underdamped oscillations and their propagation beyond the optically excited depth are at odds with the observation of the overdamped nature of the amplitude mode measured using meV-resolution inelastic x-ray scattering and polarized Raman scattering. The ωAM is found to decrease with increasing fluence owing to a rise in the sample temperature
which is independently confirmed using polarized Raman scattering and ab-initio molecular dynamics simulations. We rationalize the above observations by explicitly calculating two coupled quasiparticles—phonon–polariton and exciton–polariton. Our data and simulations cannot conclusively confirm or rule out the one but point toward the likely origin from propagating phonon–polariton. The observed non-local behavior of amplitude mode thus provides an opportunity to engineer material properties at a substantially faster time scale with optical pulses.
Amplitude mode is collective excitation emerging from frozen lattice distortions below the charge-density-wave (CDW) transition temperature TCDW and relates to the order parameter. Generally
the amplitude mode is non-polar (symmetry-even) and does not interact with incoming infrared photons. However
if the amplitude mode is polar (symmetry-odd)
it can potentially couple with incoming photons
thus forming a coupled phonon–polariton quasiparticle that can travel with light-like speed beyond the optically excited region. Here
we present the amplitude mode dynamics far beyond the optically excited depth of ∼150 nm in the CDW phase of ∼10-μm-thick single-crystal EuTe4 using time-resolved x-ray diffraction. The observed oscillations of the CDW peak
triggered by photoexcitation
occur at the amplitude mode frequency ωAM. However
the underdamped oscillations and their propagation beyond the optically excited depth are at odds with the observation of the overdamped nature of the amplitude mode measured using meV-resolution inelastic x-ray scattering and polarized Raman scattering. The ωAM is found to decrease with increasing fluence owing to a rise in the sample temperature
which is independently confirmed using polarized Raman scattering and ab-initio molecular dynamics simulations. We rationalize the above observations by explicitly calculating two coupled quasiparticles—phonon–polariton and exciton–polariton. Our data and simulations cannot conclusively confirm or rule out the one but point toward the likely origin from propagating phonon–polariton. The observed non-local behavior of amplitude mode thus provides an opportunity to engineer material properties at a substantially faster time scale with optical pulses.
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